Breakaway

 
» Download Breakaway 2.0.1 for Mac OS X 10.3 or later

Code mentioned in the video:

if application "VLC" is running then
    tell application "VLC"
        if playing then
            tell application "System Events" to tell process "VLC"
                click menu item "Pause" of menu 1 of menu bar item "Playback" of menu bar 1
            end tell
        end if
    end tell
end if 







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